Product ID:5471, MOLDIT D CASTABLE & GUN MIX
MSDS Date:11/01/1985
FSC:5640
NIIN:00N029865
MSDS Number: BNNRZ

C-E REFRACTORIES

VALLEY FORGE, PA 19482
US

Emergency Phone: 215-337-1100;203-285-9693

Info Phone: 215-337-1100

Cage: 8C482

C-E REFRACTORIES DIV OF COMBUSTION ENGINEERING

KING OF PRUSSIA, PA 19406 US

Telephone: 215-337-1100

Cage: 8C482

AIR SUPPLIED RESPIRATOR.

RTECS: 9999999ZZ

CRYSTALLINE SILICA

Fraction By Weight: >1%

10 MG/M3 TDUST;5

CAS: 1344-28-1

RTECS: BD1200000

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

SILICA, CRYSTALLINE - FUSED

CAS: 60676-86-0

RTECS: VV7328000

OSHA PEL SEE TABLE Z3

ACGIH TLV: 0.1 MG/M3 RDUST;9293

CALCIUM OXIDE; (CAO)

CAS: 1305-78-8

RTECS: EW3100000

OSHA PEL 5 MG/M3

ACGIH TLV: 2 MG/M3

HEMATITE; (FE*2O*3)

CAS: 1317-60-8

RTECS: MH7600000

OSHA PEL 10 MG/M3 TDUST

ACGIH TLV: 5 MG/M3 FUME

TITANIUM OXIDE; (TIO*2)

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

ALKALI OXIDES; (ALKALIES)

WEAR PROTECTIVE CLOTHING & VACUUM CLEAN PRIOR TO

RTECS: 9999999ZZ

EXPOSURE TO DUST CONTAINING CRYSTALLINE SILICA, THE

RTECS: 9999999ZZ

FREE SILICA WORK AREA, AVOID

RTECS: 9999999ZZ

PEL USE NIOSH/MSHA APPROVED FULL FACEPIECE RESP

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:MOLDIT D CAN CAUSE IRRITATION TO THE
EYES ON CONTACT AND TO THE SKIN ON PROLONGED CONTACT. CHRONIC HLTH
HAZARDS CAN OCCUR FROM LONG TERM EXCESS INHAL OF CRYSTALLINE SILICA
DUST. CRYSTALLINE SILICA IN THE LUNGS CAN PRODUCE A PNEUM,
COMMONLYCALLED SILICOSIS, WHICH IS A SLOWLY DEVELOPING DISEASE.
SYMP (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CRYSTALLINE SILICA: GROUP 2A (IARC).
Effects of Overexposure:HLTH HAZ: ARE USUALLY DELAYED (10 YEARS OR
MORE). SMOKING CAN INCREASE THE RISK OF INJURY.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE: FLUSH THOROUGHLY (AT LEAST 15 MINUTES) WITH WATER. CALL
MD. SKIN: WASH OFF THOROUGHLY USING A MILD SOAP AND WATER. INGEST:
CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHIN
G (GIVE O2/ARTF RESP) .

Flash Point:NON-COMBUSTIBLE
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE TO THE
SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . THIS PRODUCT IS A NON-COMBUSTIBLE
REFRACTORY.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:IN CASE OF MAJOR SPILLS PROVIDE VENTILATION.
CLEANUP PERSONNEL NEED PROTECTION AGAINST EYE CONTACT, INHALATION
OF DUST AND PROLONGED SKIN CONTACT. PICK UP SPILLS TAKING CARE TO
AVOID RAISING DUST CLOU DS (USE VACUUM WHERE NECESSARY).
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:BECAUSE OF POSS PRESENCE OF CRYSTALLINE SILICA IN
USED REFRACTORY LININGS, PARTICULAR CARE SHOULD BE EXERCISED DURING
TEAR-OUT TO MINIMIZE THE GENERATION OF DUST. ADHERENCE TO PROPER
METHODS OF DUST S UPPRESSION & CONTROL IS (SUPP DATA)

Respiratory Protection:PROVIDE WORKERS WITH NIOSH/MSHA APPROVED DUST
RESP FOR USE IN EMERGENCY OR NONROUTINE SITUATIONS WHERE DUST
LEVELS MAY EXCEED PEL. A NIOSH/MSHA APPRVD HALF FACEPIECE RESP CAN
BE USED FOR EXPOS UP TO 1 0X PEL. FOR EXPOS UP TO 100X (ING 11)
Ventilation:PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION TO
MEET PEL REQUIREMENTS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROTECTIVE CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
OTHER PREC:IMPERATIVE. FOLLOWING ARE RECOMMENDED PREC TO BE TAKEN
DURING REMOVAL: EMPLOYEES SHOULD BE APPRISED OF HAZ & PROPER CNDTNS
& PREC FOR SAFE USE/EXPOS. NIOSH/MSHA APPRVD RESP SHOULD BE USED F
OR DUST LEVELS BELOW 50 MG/M3. DUST GENERATION SHOULD BE MINIMIZED
BY USE OF DUST CONTROL EQUIP/WATER SPRAY. (ING 8)

HCC:N1
Appearance and Odor:BROWN, ODORLESS, GRANULAR MATERIAL.

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:MOISTURE CAN CAUSE PREMATURE
CONSOLIDATION.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods:USE WASTE CONTAINERS SUITABLE FOR TRANSPORTATION
AND DISPOSE OF MATLS IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS. NON-BIODEGRADABLE - USE SOLID WASTE DISPOSAL COMMON TO
LANDFILL TYPE OPER ATION OR SIMILAR DISPOSAL.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.